Student Work

Investigation of Triphenylacetic Acid as a Trapping Agent for Sealing Molecular Guests Within Porous Metal-Organic Frameworks

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Trapping of guests within MOF-5 was investigated by reacting solutions containing MOF particles and guest compound with zinc nitrate and triphenylacetic acid (trapping agent), then monitoring desorption of the guest from the resulting loaded, sealed MOF. This research demonstrated coating the surface of loaded MOF particles with a bulky, sterically-demanding monocarboxylic acid is a highly effective approach for trapping guests within MOFs.

  • This report represents the work of one or more WPI undergraduate students submitted to the faculty as evidence of completion of a degree requirement. WPI routinely publishes these reports on its website without editorial or peer review.
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Identifier
  • E-project-043015-001300
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Year
  • 2015
Date created
  • 2015-04-30
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Permanent link to this page: https://digital.wpi.edu/show/cc08hh351